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Cage effect : ウィキペディア英語版
Cage effect

The cage effect in chemistry describes how properties of a molecule are affected by its surroundings.
In a solvent a molecule is often more accurately described existing in a cage of solvent molecules, the so-called solvent cage. Reactions occur when a molecule occasionally "jumps out" and meets another molecule. Typical cage lifetime in a solvent cage is 10−11s.
Other examples include how in a gas at low pressure a normally highly reactive and short lived molecule can be contained.
Also, specific host-guest interactions occur in inclusion compounds.



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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